Scientists have reached a new low
in the cooling of liquid water, hitting -45 degrees Celsius (-49 degrees
Fahrenheit). That's way below the usual freezing point, and shows we still have
a lot to learn about the physics of this plentiful substance.
In two separate experiments,
water was supercooled right down to 230 Kelvin and 227.7 Kelvin, which is
-43.15°C (-45.67°F) and -45.45°C (-49.81°F), respectively. At these kind of
extreme temperatures, it's almost as if water becomes two different types of
liquid, the scientists say – fluctuating between two different states in the
same way that we might deliberate over a decision. We already know that water
can stay as a liquid below zero degrees Celsius (32°F) in certain situations,
such as clouds high up in the atmosphere. In fact, the freezing effect is
dependent on a number of factors affecting the molecules inside water and how
quickly they crystallise. Scientists have previously been able to delay this
freezing, which happens when an initial crystal nucleus forms and begins
attracting other molecules, but so far no one's sure just how cold we can get
water and still keep its molecules flowing.
"The new remarkable property
is that we find that water can exist as two different liquids at low
temperatures where ice crystallisation is slow," says one of the
researchers, Anders Nilsson from Stockholm University in Sweden. Nilsson and
his colleagues were the ones to hit 227.7 Kelvin, using microscopic droplets of
water propelled into a vacuum (the smaller the droplet, the easier it is to
keep from freezing). Using advanced X-ray scans, they noticed water of two
different densities coexisting together. The researchers saw "how a glassy
state of water transforms into a viscous liquid which almost immediately
transforms to a different, even more viscous liquid of much lower
density," says one of the team, Katrin Amann-Winkel from Stockholm
University.
This coexistence of two densities
at a certain super-cool temperature has in fact been predicted before, but this
is the first evidence we've seen of it actually being real – evidence that
could inform many different areas of research, from food preservation to
cryogenics (you wouldn't want your body icing up on a deep space trip, after
all). The second experiment, run by a different international team of
researchers, again used microscopic droplets of water inside a vacuum. This
time the study demonstrated how the extremely low pressure levels produced
evaporation cooling that outpaced the crystallisation process. That led to the
ultra-low cooling point of 230 Kelvin before freezing began to take place.
Special laser techniques were required, measuring the size of droplets to gauge
their temperature, and this same approach could be used again to study
super-cooled water in the future, the researchers say. "The easiest way to
determine the temperature of a spherical droplet was to measure its size, which
can be accurately determined by exploiting the presence of an interference
pattern in the light scattered by the droplet," senior author, Robert
Grisenti from the University of Frankfurt in Germany, told Sam Jarman at
Physics World.
Eventually, the technique could
even be adapted to measure droplets in the Earth's atmosphere, and improve our
understanding of the planet's changing climate. This is the first time we've
been able to observe liquid water at such a low temperature, which means
there's still some debate over how accurate these readings are and whether we
can push them any further. What everyone seems to agree on is that these are
important areas of research for understanding more about the properties of
water, which is key to the health of our planet and life itself. And we now
have a new perspective on it. As one of the researchers from the first
experiment, Lars G.M. Pettersson from Stockholm University puts it: "In a
nutshell: Water is not a complicated liquid, but two simple liquids with a complicated
relationship." The research has been published in Science and Physical
Review Letters.
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